I think the answer has been covered fully here, but here is my experience with it.
My first tank had been set up for approximately 6 months before I started to see a couple purple spots appear. These quickly grew at a rapid pace until one day, they all started turning white. All of my parameters were in line so I couldn't figure out what the problem was, but just continued to do what I was doing.
A couple of months down the road, it started coming back with a vengeance.
Now, I have to constantly scrape the glass so that I can see inside my tank.
As for my second tank, I started that one out with dry rock. After acquiring some frags that had some nice purple coralline spots on them, they started to slowly begin colonizing the rocks and glass. I would say that it took approximately 4-6 months before it started aggressively growing.
I do use kalkwasser in my top off water so that my parameters are inline and can cope with the requirements of the coralline.
I guess in short, if you purchase frags with coralline on them, that will start colonizing your tank, and then after that, it just takes time. There aren't any supplements I would waste money on. Just keep your parameters in line and give it time.
Hope this helps.